Investigation of the Rheological Properties of Asphalt Binders Modified with Nanomaterial
Abstract
This study examined the effects of the Aerosil 150 addition on the rheological characteristics of bituminous binders at various temperatures. In the study, a frequency sweep test was applied to determine the rheological properties of pure binders and binders with 2%, 4% and 6% Aerosil 150 additives. Unaged binders were subjected to the frequency sweep test using a Bohlin DSR rheometer at test temperatures ranging from 40°C to 80°C (increasing by 10°C). The results showed that adding Aerosil 150 additive to the pure binder raised the binder's complex modulus (G*) values while decreasing the phase angle (δ) values. At 40 °C 0.1 Hz frequency, 2%, 4% and 6% Aerosil 150 doped binders gave G* values 1.52, 2.02 and 3 times higher than pure binder, respectively. The same ratio is 1.31, 1.54 and 1.99 times at 5 Hz frequency and 1.28, 1.47 and 1.82 times at 10 Hz frequency. At the same temperature, as the frequency value increases, the binders' complex modulus values approach each other. When the phase angle values at 40°C were examined, the 2%, 4%, and 6% Aerosil 150 modified binders, when compared to pure binder at 0.1 Hz frequency, yielded 2.75°C, 5.56°C, and 9.17°C lower phase angle values, respectively. This decrease is 3.19, 5.04 and 7.33 °C at 5 Hz frequency and 3.09, 4.84 and 6.76 °C at 10 Hz frequency. This shows that at various frequencies, the modified binder behaves more adaptably than the pure binder. The fact that the binder has a low δ value against a high G* value indicates that it will exhibit more flexible behavior. It was discovered as a result that Aeresil 150 modified binders performed better in terms of rheological qualities than pure binders.
References
- 1.N. Bala, M. Napiah, and I. Kamaruddin, “Nanosilica composite asphalt mixtures performance-based design and optimisation using response surface methodology,” Int. J. Pavement Eng., vol. 21, no. 1, pp. 29–40, Jan. 2020, doi: 10.1080/10298436.2018.1435881.DOI
- 2.D. Kong, X. Du, S. Wei, H. Zhang, Y. Yang, and S. P. Shah, “Influence of nano-silica agglomeration on microstructure and properties of the hardened cement-based materials,” Constr. Build. Mater., vol. 37, pp. 707–715, Dec. 2012, doi: 10.1016/J.CONBUILDMAT.2012.08.006.DOI
- 3.A. Parviz, “Nano materials in asphalt and tar,” Aust. J. Basic Appl. Sci., vol. 5, no. 12, pp. 3270–3273, 2011.
- 4.J. Teizer, M. Venugopal, W. Teizer, and J. Felkl, “Nanotechnology and Its Impact on Construction: Bridging the Gap between Researchers and Industry Professionals,” J. Constr. Eng. Manag., vol. 138, no. 5, pp. 594–604, May 2012, doi: 10.1061/(ASCE)CO.1943-7862.0000467.DOI
- 5.J. Yang and S. Tighe, “A Review of Advances of Nanotechnology in Asphalt Mixtures,” Procedia - Soc. Behav. Sci., vol. 96, no. Cictp, pp. 1269–1276, 2013, doi: 10.1016/j.sbspro.2013.08.144.DOI
- 6.E. Santagata, O. Baglieri, L. Tsantilis, and D. Dalmazzo, “SIIV - 5th International Congress - Sustainability of Road Infrastructures Rheological Characterization of Bituminous Binders Modified with Carbon Nanotubes,” Procedia - Soc. Behav. Sci., vol. 53, pp. 546–555, 2012, doi: 10.1016/j.sbspro.2012.09.905.DOI
- 7.M. Saltan, S. Terzi, and S. Karahancer, “Examination of hot mix asphalt and binder performance modified with nano silica,” Constr. Build. Mater., vol. 156, pp. 976–984, Dec. 2017, doi: 10.1016/j.conbuildmat.2017.09.069.DOI
- 8.H. Taherkhani and S. Afroozi, “The properties of nanosilica-modified asphalt cement,” Pet. Sci. Technol., vol. 34, no. 15, pp. 1381–1386, 2016, doi: 10.1080/10916466.2016.1205604.DOI
- 9.S. I. Sarsam, “Effect of Nano Materials on Asphalt Cement Properties,” Int. J. Sci. Res. Knowl., pp. 422–426, Oct. 2013, doi: 10.12983/ijsrk-2013-p422-426.DOI
- 10.F. S. Bhat and M. S. Mir, “Performance evaluation of nanosilica-modified asphalt binder,” Innov. Infrastruct. Solut., vol. 4, no. 1, pp. 1–10, 2019, doi: 10.1007/s41062-019-0249-5.DOI
- 11.H. Ezzat, S. El-Badawy, A. Gabr, E. S. I. Zaki, and T. Breakah, “Evaluation of Asphalt Binders Modified with Nanoclay and Nanosilica,” Procedia Eng., vol. 143, no. Ictg, pp. 1260–1267, 2016, doi: 10.1016/j.proeng.2016.06.119.DOI
- 12.D. I. Alhamali, J. Wu, Q. Liu, N. A. Hassan, N. I. M. Yusoff, and S. I. A. Ali, “Physical and Rheological Characteristics of Polymer Modified Bitumen with Nanosilica Particles,” Arab. J. Sci. Eng., vol. 41, no. 4, pp. 1521–1530, 2016, doi: 10.1007/s13369-015-1964-7.DOI
- 13.F. S. Bhat and M. S. Mir, “Rheological investigation of asphalt binder modified with nanosilica,” Int. J. Pavement Res. Technol., vol. 14, no. 3, pp. 276–287, 2021, doi: 10.1007/s42947-020-0327-2.DOI
- 14.G. Shafabakhsh, M. Rajabi, and A. sahaf, “The fatigue behavior of SBS/nanosilica composite modified asphalt binder and mixture,” Constr. Build. Mater., vol. 229, p. 116796, 2019, doi: 10.1016/j.conbuildmat.2019.116796.DOI
- 15.G. Airey, J. E. Sias, G. M. Rowe, H. Di Benedetto, C. Sauzéat, and E. V. Dave, “An Overview of Black Space Evaluation of Performance and Distress Mechanisms in Asphalt Materials,” in RILEM Bookseries, Springer, Cham, 2022, pp. 231–237.
- 16.C. Grosse, “A program for the fitting of Debye, Cole–Cole, Cole–Davidson, and Havriliak–Negami dispersions to dielectric data,” J. Colloid Interface Sci., vol. 419, pp. 102–106, Apr. 2014, doi: 10.1016/j.jcis.2013.12.031.DOI
- 17.A. A. Khamzin, R. R. Nigmatullin, and I. I. Popov, “Log-periodic corrections to the Cole–Cole expression in dielectric relaxation,” Phys. A Stat. Mech. its Appl., vol. 392, no. 1, pp. 136–148, Jan. 2013, doi: 10.1016/j.physa.2012.08.011.DOI
- 18.M. Jamal and F. Giustozzi, “Chemo-rheological Investigation on Waste Rubber-Modified Bitumen Response to Various Blending Factors,” Int. J. Pavement Res. Technol., vol. 15, no. 2, pp. 395–414, Mar. 2022, doi: 10.1007/s42947-021-00045-x.DOI
- 19.M. Akpolat, “Investigation of rutting, fatigue and cracking resistance parame-ters of CR modified warm asphalt binders compare with SBS modified binders,” Rev. la construcción, vol. 21, no. 2, pp. 309–328, 2022, doi: 10.7764/RDLC.21.2.309.DOI
Akpolat, M. (2023). Investigation of the Rheological Properties of Asphalt Binders Modified with Nanomaterial. *The European Journal of Research and Development*, 3(1), 97-107. https://doi.org/10.56038/ejrnd.v3i1.237
Bibliographic Info
More from The European Journal of Research and Development
The Bleaching of Woven Fabrics Using the Foam Application Technique
Aylin Kuşen, Onur Balcı, Koray Pektaş
2026 · Vol 6 · Issue 1
Automated Monkeypox Disease Classification Using Texture and Focus-Based Image Features
Tuğba Şentürk, Çiğdem Gülüzar Altıntop, Fatma Latifoğlu
2026 · Vol 6 · Issue 1
EEG-Based Assessment of Stress Levels Using Time–Frequency Features and Machine Learning
Sevde Samsa, Çiğdem Gülüzar Altıntop
2026 · Vol 6 · Issue 1
A Compact Non-Intrusive Measurement System for Critical Dimensions and Calibration Chart Generation of Underground Fuel Tanks
İlker Değirmencioğlu, Savaş Barış, Yusuf Kaya
2025 · Vol 5 · Issue 1
Investigation of the Comfort and Quality Properties of Knitted Garments Produced with Raised Yarn
Yusuf Koç, Serkan Karabıyık, Azize Çoban
2025 · Vol 5 · Issue 1
A Web-Based Credit Card Payment Architecture for Dealer Portals: Android POS Integration, Microservice Design, and Behavioural Segmentation for Data-Driven Dealer Management
Adnan Erdogan, Hüseyin Oktay Altun
2025 · Vol 5 · Issue 1